Drug Monograph

Edaravone

Radicava, Radicava ORS

Free Radical Scavenger (Substituted 2-Pyrazolin-5-one) · IV Infusion & Oral Suspension
Pharmacokinetic Profile
Half-Life
4.5–9 h
Metabolism
Sulfotransferases & UGTs
Protein Binding
92% (albumin)
Bioavailability (Oral)
~57% (fasted)
Volume of Distribution
63.1 L (IV)
Clinical Information
Drug Class
Free Radical Scavenger
Available Doses
IV: 30 mg/100 mL bag; Oral: 105 mg/5 mL suspension
Route
IV infusion & Oral (or via feeding tube)
Renal Adjustment
None required (mild-moderate)
Hepatic Adjustment
None required
Pregnancy
Potential fetal harm (animal data)
Lactation
Unknown in humans; excreted in rat milk
Schedule / Legal Status
Rx only (not a controlled substance); Orphan Drug
Generic Available
IV generic available; Oral (brand only)
Rx

Indications

IndicationApproved PopulationTherapy TypeStatus
Amyotrophic lateral sclerosis (ALS)AdultsDisease-modifying (may be used alongside riluzole)FDA Approved

Edaravone is one of a limited number of agents approved specifically for ALS. The pivotal trial (Study 19) enrolled patients with early-stage disease — those who were functionally independent, had definite or probable ALS per the revised El Escorial criteria, forced vital capacity of at least 80% predicted, and disease duration under two years. The drug slowed the decline in daily functioning over a 24-week period as measured by the ALSFRS-R. It does not reverse existing motor neuron damage and has not been shown to extend survival.

Off-Label Uses

Acute ischaemic stroke (Japan, South Korea, other Asian markets): Edaravone has been approved for stroke recovery in Japan since 2001. It is not approved for stroke in the US or EU. Evidence quality: Moderate (post-marketing data and retrospective studies, no large Western RCTs).

Dose

Dosing

Clinical ScenarioStarting DoseMaintenance DoseMaximum DoseNotes
ALS — initial treatment cycle (IV)60 mg IV daily × 14 days60 mg IV daily (10 of 14 days)60 mg/dayInfuse over 60 min as two consecutive 30 mg bags (~1 mg/min). Each cycle: 14 days on, 14 days off (cycle 1); then 10 of 14 days on, 14 days off (subsequent).
Brand IV (Radicava) discontinued in US April 2025; IV generics remain available.
ALS — initial treatment cycle (Oral)105 mg PO daily × 14 days105 mg PO daily (10 of 14 days)105 mg/dayTake in morning after overnight fast. No food for 1 h after dose (water permitted). 5 mL via provided oral syringe or feeding tube.
See fasting table below for meal-specific intervals.
Switch from IV to oral formulation105 mg PO daily105 mg PO daily105 mg/dayMaintain the same dosing frequency and cycle timing. Oral 105 mg provides equivalent AUC to IV 60 mg.
Can switch at any point within a cycle.
ALS — mild-moderate renal impairmentNo dose adjustment requiredExposure increases are clinically non-significant (~20–29% AUC rise with moderate renal impairment). Severe impairment not studied.
Monitor renal function at baseline.
ALS — hepatic impairment (any severity)No dose adjustment requiredExposure changes across mild, moderate, and severe hepatic impairment are not clinically significant (FDA PI).

Oral Fasting Requirements

Meal TypeFast Before DoseFast After Dose
High-fat meal (800–1,000 kcal, 50% fat)8 hours1 hour
Low-fat meal (400–500 kcal, 25% fat)4 hours1 hour
Caloric supplement (~250 kcal, e.g., protein drink)2 hours1 hour
Clinical Pearl: Dosing Cycle Structure

Edaravone uses an unusual cyclic regimen. The first cycle is 14 consecutive daily doses followed by a 14-day drug-free period. All subsequent cycles consist of 10 dosing days within a 14-day period (typically weekdays for two weeks, omitting weekends), followed by a 14-day drug-free period. Patients and caregivers benefit from a written calendar marking “on” and “off” days to maintain adherence.

PK

Pharmacology

Mechanism of Action

The precise mechanism by which edaravone slows functional decline in ALS has not been established. Edaravone is a synthetic free radical scavenger belonging to the substituted 2-pyrazolin-5-one class. Under physiological conditions, the molecule partially exists as an anion capable of donating electrons to reactive oxygen and nitrogen species, including hydroxyl radicals and peroxynitrite. By neutralising these species, edaravone is thought to reduce oxidative stress — a process broadly implicated in motor neuron degeneration. Preclinical work in SOD1-mutant mouse models showed that edaravone administration attenuated motor neuron loss and delayed symptom progression. However, the clinical benefit may not be fully explained by antioxidant activity alone, and the drug has not been shown to affect survival or reverse existing neuronal damage in humans.

ADME Profile

ParameterValueClinical Implication
AbsorptionOral Tmax ~0.5 h (fasted); absolute bioavailability ~57% due to first-pass effect; high-fat meal reduces Cmax by 82% and AUC by 61%Strict fasting requirements are essential for consistent drug exposure; non-adherence to fasting substantially reduces absorption
DistributionVd = 63.1 L (IV); 92% protein bound (albumin); no concentration-dependent bindingModerate tissue distribution; protein-binding displacement interactions unlikely at therapeutic concentrations
MetabolismSulfate conjugate (sulfotransferases) and glucuronide conjugate (UGT1A1, 1A6, 1A7, 1A8, 1A9, 1A10, 2B7, 2B17); both metabolites inactiveNon-CYP metabolism means minimal risk of CYP-based drug interactions; multiple redundant UGT pathways reduce pharmacogenomic variability
Eliminationt½ = 4.5–9 h; CL = 35.9 L/h (IV); urinary excretion 60–80% as glucuronide, 6–8% as sulfate, <1% unchangedOnce-daily dosing is sufficient; no accumulation with repeated daily administration; renal elimination predominates
SE

Side Effects

≥10% Very Common
Adverse EffectIncidenceClinical Note
Contusion (bruising)15% (vs 9% placebo)Most commonly reported adverse effect; may reflect disease-related falls rather than a direct pharmacological effect; counsel patients on fall prevention
Gait disturbance13% (vs 9% placebo)Likely multifactorial — overlaps with ALS progression; assess new or worsening gait changes to distinguish drug effect from disease course
Headache10% (vs 6% placebo)Usually mild and self-limiting; routine analgesics may be used as needed
1–10% Common
Adverse EffectIncidenceClinical Note
Dermatitis8% (vs 5% placebo)Non-specific; monitor for progression to more severe skin reactions
Eczema7% (vs 4% placebo)Manage with emollients and topical corticosteroids if needed
Fatigue7.6% (oral formulation, open-label)Observed in the RADICAVA ORS open-label study; overlaps significantly with ALS-related fatigue
Respiratory failure / disorder / hypoxia6% (vs 4% placebo)Difficult to separate from ALS disease progression; monitor respiratory function routinely
Glycosuria4% (vs 2% placebo)Clinical significance unclear; not associated with hyperglycaemia in trials
Tinea infection4% (vs 2% placebo)Superficial fungal infections; treat with standard topical antifungals
Serious Serious (Regardless of Frequency)
Adverse EffectEstimated FrequencyTypical OnsetRequired Action
AnaphylaxisRareDuring or shortly after infusion/doseImmediate discontinuation; emergency care (epinephrine, airway management); permanent discontinuation of edaravone
Hypersensitivity reactions (urticaria, erythema multiforme, decreased BP, dyspnoea)RareAny time during treatmentDiscontinue edaravone; treat per standard of care and monitor until resolution; do not rechallenge
Sulfite allergic reaction (asthmatic episodes)Rare (higher risk in asthmatics)After any dose (contains sodium bisulfite)Discontinue; manage bronchospasm; assess sulfite allergy history before initiation
Neurotoxicity (spinal cord white matter vacuolation)Not observed in humans at approved dosesSeen in 39-week dog study at supratherapeutic dosesNo clinical action required at current doses; safety margin is approximately 2-fold above human exposure at approved dose. Report any unexplained neurological symptoms
Discontinuation Discontinuation Rates
Edaravone (IV) Arm
1% due to adverse events
Context: In the pivotal Study 19, only 1 patient (1.4%) in the edaravone arm discontinued due to an adverse event (dysphagia), compared with 4 patients (5.9%) in the placebo arm
Serious Adverse Events
16% vs 24% placebo
Top reasons: Dysphagia, respiratory disorder, speech disorder (predominantly ALS progression events)
Reason for DiscontinuationIncidenceContext
Dysphagia1.4% (edaravone)Likely disease progression rather than drug effect
Respiratory disorder0% (edaravone) vs 1.5% (placebo)No respiratory-related discontinuations in active arm
Managing Hypersensitivity Risk

Both formulations contain sodium bisulfite. Before starting edaravone, screen for asthma history and known sulfite sensitivity. During IV infusions, keep the patient under direct observation for the duration of the 60-minute infusion and have emergency medications available. For oral administration, instruct patients to recognise early signs of allergic reactions (hives, swelling, breathing difficulty) and seek immediate care.

Int

Drug Interactions

Edaravone has a notably clean interaction profile. It is metabolised by sulfotransferases and multiple UGT isoforms rather than CYP450 enzymes. In vitro and clinical studies confirm that edaravone does not significantly inhibit or induce CYP enzymes (1A2, 2B6, 2C8, 2C9, 2C19, 2D6, 3A), UGTs, or major drug transporters (P-gp, OATP1B1/1B3, OAT1, OCT2, MATE1/2-K). No known clinically significant drug-drug interactions have been identified. In clinical studies, co-administration with sildenafil (CYP3A4 substrate), rosuvastatin (BCRP substrate), and furosemide (OAT3 substrate) produced no meaningful pharmacokinetic changes.

Minor Riluzole
MechanismNo pharmacokinetic interaction expected; riluzole is a CYP1A2 substrate while edaravone does not inhibit or induce CYP1A2
EffectNo clinically meaningful change in exposure to either drug; over 90% of pivotal trial patients used both concurrently
ManagementNo dose adjustment required; safe to co-administer
FDA PI / Study 19
Minor CYP3A4 Substrates (e.g., Sildenafil)
MechanismIn vitro and clinical data show edaravone does not inhibit or induce CYP3A4
EffectNo change in sildenafil Cmax or AUC with concomitant oral edaravone 120 mg
ManagementNo dose adjustment needed for CYP3A4 substrates
FDA PI
Minor BCRP Substrates (e.g., Rosuvastatin)
MechanismEdaravone does not inhibit BCRP at therapeutic concentrations
EffectNo change in rosuvastatin pharmacokinetics
ManagementNo dose adjustment needed
FDA PI
Minor OAT3 Substrates (e.g., Furosemide)
MechanismEdaravone does not inhibit OAT3 at recommended doses
EffectNo change in furosemide Cmax or AUC
ManagementNo dose adjustment needed
FDA PI
Interaction Profile Summary

Edaravone is one of the few ALS therapeutics with no known clinically significant drug-drug interactions. This is advantageous in ALS patients who frequently receive concomitant riluzole, baclofen, and other symptomatic medications. The non-CYP metabolism (sulfotransferases and UGTs) provides a wide therapeutic compatibility window.

Mon

Monitoring

  • Hypersensitivity Signs Every infusion / dose
    Routine
    Monitor for urticaria, erythema, wheals, dyspnoea, or hypotension during and immediately after IV infusions. For oral dosing, educate the patient and caregiver to recognise allergic signs.
  • Respiratory Function (FVC) Baseline, then every 3 months
    Routine
    Forced vital capacity should be tracked as part of standard ALS care. Decline guides decisions about non-invasive ventilation and overall disease trajectory. The pivotal trial enrolled patients with FVC ≥80% predicted.
  • ALSFRS-R Score Baseline, then every 1–3 months
    Routine
    The primary efficacy measure in the pivotal trial. Serial scores help clinicians assess treatment response and guide shared decision-making about continuing therapy.
  • Renal Function Baseline
    Routine
    Assess creatinine and eGFR before initiation. No dose adjustment needed for mild-moderate impairment. Effects of severe renal impairment have not been studied.
  • Sulfite Allergy / Asthma Status Before first dose
    Trigger-based
    Screen for asthma and known sulfite sensitivity. Both formulations contain sodium bisulfite. Sulfite sensitivity is more common in asthmatic individuals.
  • Pregnancy Status Before initiation, then as indicated
    Trigger-based
    Animal studies showed developmental toxicity at clinically relevant doses. Advise patients of reproductive potential to use contraception and notify prescriber if pregnancy occurs.
  • Skin Reactions Each visit
    Trigger-based
    Dermatitis and eczema occur more frequently with edaravone. Evaluate new rashes for early signs of erythema multiforme or more serious hypersensitivity.
CI

Contraindications & Cautions

Absolute Contraindications

  • Known hypersensitivity to edaravone or any inactive ingredient in either formulation (including sodium bisulfite, L-cysteine hydrochloride hydrate, sorbitol). Prior anaphylaxis or erythema multiforme to edaravone is a permanent contraindication.

Relative Contraindications (Specialist Input Recommended)

  • Asthma or known sulfite sensitivity: Both RADICAVA and RADICAVA ORS contain sodium bisulfite. Sulfite-sensitive asthmatics are at elevated risk for bronchospasm and anaphylaxis. A risk-benefit discussion with allergy or pulmonology input is warranted before initiation.
  • Pregnancy: Animal reproductive studies demonstrated fetal harm (increased mortality, reduced growth, delayed development) at clinically relevant doses. No human data exist. Prescribing requires documented risk-benefit discussion with the patient.
  • Severe renal impairment: Not studied. Although mild-moderate impairment does not meaningfully alter exposure, the effects of severe impairment on edaravone and its metabolites are unknown. Specialist nephrology input is advisable.

Use with Caution

  • Breastfeeding: Edaravone and its metabolites are excreted in rat milk. No human data. Consider the risk-benefit balance.
  • Patients with swallowing difficulty: Oral suspension can be administered via NG tube or PEG tube (silicone, PVC, or polyurethane). Flush with 30 mL water before and after administration.
  • Paediatric patients: Safety and effectiveness have not been established in children.
FDA Safety Advisory Hypersensitivity and Sulfite Sensitivity

Edaravone does not carry an FDA Boxed Warning. However, the FDA label includes prominent Warnings and Precautions for hypersensitivity reactions (including anaphylaxis reported in post-marketing surveillance) and sulfite allergic reactions. Both formulations contain sodium bisulfite, which may cause severe or life-threatening allergic-type reactions, particularly in asthmatic individuals. Clinicians should have emergency medications available during IV infusions and educate patients on oral formulation about recognising allergic symptoms.

Pt

Patient Counselling

Purpose of Therapy

Edaravone is a disease-modifying treatment for ALS that aims to slow the rate of functional decline. It does not cure ALS, reverse existing damage, or restore lost motor function. In the pivotal clinical trial, patients who received edaravone experienced a slower decline in daily activities (such as writing, eating, walking, and breathing) compared to those receiving placebo over a six-month period. Patients should understand that the treatment works alongside other ALS management strategies including riluzole, physical therapy, and nutritional support.

How to Take (Oral Formulation)

RADICAVA ORS is taken once daily in the morning on an empty stomach. Patients should shake the bottle vigorously upside-down for at least 30 seconds before each use. The dose is 5 mL (105 mg) drawn up with the provided oral syringe — household teaspoons must not be used. Patients must not eat food for at least 1 hour after taking the dose (water is permitted). Opened bottles must be discarded after 15 days, regardless of remaining volume.

Fasting Requirements
Tell patient The drug is poorly absorbed with food. If you ate a large meal (high-fat) the night before, wait at least 8 hours before taking your dose. A lighter meal requires a 4-hour fast; a small snack or protein drink requires a 2-hour fast. After the dose, wait 1 hour before eating. Plan to take the medication first thing in the morning after sleeping to meet these fasting windows most easily.
Call prescriber If unable to maintain the required fasting schedule due to nutritional needs, weight loss, or PEG tube feeding schedules, contact your care team to adjust the timing.
Cyclic Dosing Schedule
Tell patient Edaravone uses an alternating on/off schedule. Your first cycle is 14 consecutive days of treatment, then 14 days off. After that, each cycle is 10 treatment days within a 14-day period, then 14 days off. Ask your pharmacist or care team for a dosing calendar. If you miss a dose, do not double up the next day.
Call prescriber If you are confused about which days to take the medication or have missed several doses in a row.
Allergic Reactions
Tell patient This medication contains sodium bisulfite, which can cause allergic reactions, especially in people with asthma. Learn to recognise signs: hives, swelling of the face, lips, or tongue, difficulty breathing, wheezing, dizziness, or feeling faint.
Call prescriber Seek emergency medical care immediately if you develop any signs of an allergic reaction. Do not take another dose until cleared by your doctor.
Storage & Handling
Tell patient Store RADICAVA ORS upright at room temperature (20–25°C / 68–77°F), protected from light. Once opened, use within 15 days. Discard any unused suspension after 15 days or 30 days from the shipment date on the pharmacy label, whichever comes first.
Call prescriber If the medication has changed colour or consistency, or if you are unsure whether it is still usable.
Pregnancy & Breastfeeding
Tell patient Animal studies have shown that edaravone may harm a developing fetus. There are no adequate studies in pregnant women. If you are of childbearing potential, discuss contraception with your care team.
Call prescriber Notify your doctor immediately if you become pregnant or plan to become pregnant, or if you are considering breastfeeding.
Ref

Sources

Regulatory (PI / SmPC)
  1. RADICAVA and RADICAVA ORS (edaravone) Prescribing Information. Mitsubishi Tanabe Pharma America, Inc. Jersey City, NJ; Revised 05/2022. FDA Label Primary source for all dosing, pharmacokinetic, safety, and contraindication data in this monograph.
  2. RADICAVA (edaravone injection) Prescribing Information. Initial approval 2017. FDA Label (2017) Original IV-only prescribing information; source for early PK data and IV-specific administration details.
  3. FDA Drug Approval Package: RADICAVA ORS (NDA 215446). U.S. Food and Drug Administration. Approved May 2022. FDA Approval Regulatory approval documentation for the oral suspension formulation including bioequivalence data.
Key Clinical Trials
  1. Writing Group; Edaravone (MCI-186) ALS 19 Study Group. Safety and efficacy of edaravone in well defined patients with amyotrophic lateral sclerosis: a randomised, double-blind, placebo-controlled trial. Lancet Neurol. 2017;16(7):505–512. doi:10.1016/S1474-4422(17)30115-1 Pivotal phase III trial (Study 19) that demonstrated a 2.49-point ALSFRS-R benefit vs placebo at 24 weeks and formed the basis for FDA approval.
  2. Abe K, Itoyama Y, Sobue G, et al. Confirmatory double-blind, parallel-group, placebo-controlled study of efficacy and safety of edaravone (MCI-186) in amyotrophic lateral sclerosis patients. Amyotroph Lateral Scler Frontotemporal Degener. 2014;15(7–8):610–617. doi:10.3109/21678421.2014.959024 Earlier phase III trial (Study 16) that did not reach its primary endpoint in the full ALS population; post-hoc analysis informed Study 19 design.
  3. Writing Group on Behalf of the Edaravone (MCI-186) ALS 19 Study Group. Open-label 24-week extension study of edaravone (MCI-186) in amyotrophic lateral sclerosis. Amyotroph Lateral Scler Frontotemporal Degener. 2017;18(sup1):55–63. doi:10.1080/21678421.2017.1364269 24-week open-label extension of Study 19 providing longer-term safety and efficacy follow-up data through 48 weeks total treatment.
Guidelines
  1. Miller RG, Jackson CE, Kasarskis EJ, et al. Practice parameter update: The care of the patient with amyotrophic lateral sclerosis: multidisciplinary care, symptom management, and cognitive/behavioral impairment (an evidence-based review). Neurology. 2009;73(15):1227–1233. doi:10.1212/WNL.0b013e3181bc01a4 AAN guideline for ALS care; predates edaravone approval but remains the foundational ALS management framework referenced by most US centres.
  2. Leigh PN, Swash M, Iwasaki Y, et al. Amyotrophic lateral sclerosis: a consensus viewpoint on designing and implementing a clinical trial. Amyotroph Lateral Scler Other Motor Neuron Disord. 2004;5(2):84–98. doi:10.1080/14660820410020187 Consensus document on ALS trial design that informed the methodology of the edaravone development programme.
Mechanistic / Basic Science
  1. Hardiman O, van den Berg LH. Edaravone: a new treatment for ALS on the horizon? Lancet Neurol. 2017;16(7):490–491. doi:10.1016/S1474-4422(17)30163-1 Expert commentary on Study 19 results, discussing the clinical significance and limitations of the trial findings.
  2. Takei K, Watanabe K, Yuki S, Akimoto M, Sakata T, Palumbo J. Edaravone and its clinical development for amyotrophic lateral sclerosis. Amyotroph Lateral Scler Frontotemporal Degener. 2017;18(sup1):5–10. doi:10.1080/21678421.2017.1353101 Review of the edaravone clinical development programme from preclinical free radical scavenging data through pivotal trial results.
Pharmacokinetics / Special Populations
  1. Ali ZK, Baker DE. Formulary drug review: edaravone. Hosp Pharm. 2017;52(11):732–736. doi:10.1177/0018578717734877 Comprehensive formulary review covering pharmacokinetics, efficacy data, and cost considerations for hospital formulary committees.
  2. Nakamaru Y, Kinoshita S, Kawaguchi A, Takei K, Palumbo J, Suzuki M. Pharmacokinetic profile of edaravone: a comparison between Japanese and Caucasian populations. Amyotroph Lateral Scler Frontotemporal Degener. 2017;18(sup1):80–87. doi:10.1080/21678421.2017.1353100 Population PK analysis demonstrating no clinically significant racial differences in edaravone exposure between Japanese and Caucasian subjects.
  3. Turnbull J. Reappraisal of an ALS trial: unaccounted procedural risk. Lancet Neurol. 2020;19(9):717–718. doi:10.1016/S1474-4422(20)30265-9 Critical appraisal of Study 19 methodology, raising questions about procedural risk factors that may have influenced trial outcomes.