Drug Monograph

Tracleer (Bosentan)

bosentan

Dual Endothelin Receptor Antagonist (ERA) · Oral
Pharmacokinetic Profile
Half-Life
~5 h (terminal)
Metabolism
CYP2C9, CYP3A4; auto-inducer
Protein Binding
>98% (albumin)
Bioavailability
~50%
Volume of Distribution
~18 L
Clinical Information
Drug Class
Dual ETA/ETB Receptor Antagonist
Available Doses
62.5 mg, 125 mg tablets; 32 mg dispersible tablet
Route
Oral (BID dosing)
Renal Adjustment
None required
Hepatic Adjustment
Avoid if ALT/AST >3x ULN; avoid moderate-severe impairment
Pregnancy
Contraindicated (Teratogenic)
Lactation
Not recommended
Schedule
Bosentan REMS Program (active)
Generic Available
Yes
Black Box Warning
Hepatotoxicity + Embryo-Fetal Toxicity
Rx

Indications

IndicationApproved PopulationTherapy TypeStatus
PAH (WHO Group 1) — to improve exercise ability and decrease clinical worseningAdults (WHO FC II-IV)Monotherapy or combinationFDA Approved
PAH (idiopathic or congenital) — to improve pulmonary vascular resistancePediatric ≥3 yearsMonotherapyFDA Approved

Bosentan was the first oral endothelin receptor antagonist approved for PAH (2001). The pivotal trials (Study 351 and BREATHE-1) enrolled predominantly patients with idiopathic or heritable PAH (60%), connective tissue disease-associated PAH (21%), and congenital heart disease-associated PAH with left-to-right shunts (18%). Pediatric approval was granted based on PVR bridging from the BREATHE-3 study. Bosentan remains widely used globally, though its hepatotoxicity monitoring requirements and extensive drug interaction profile have shifted many prescribers toward newer ERAs such as ambrisentan and macitentan.

Off-Label Uses

Digital ulcers in systemic sclerosis: Approved in the EU (Tracleer/bosentan label) for reducing new digital ulcers. Not FDA-approved for this indication but used off-label in the US. Evidence quality: Moderate (RAPIDS-1 and RAPIDS-2 trials).

Eisenmenger syndrome (WHO Group 1 CHD-PAH): BREATHE-5 demonstrated improved 6MWD without worsening oxygen saturation. Evidence quality: Moderate.

Dose

Dosing

Adult and Adolescent Dosing — By Clinical Scenario

Clinical ScenarioStarting DoseMaintenance DoseMaximum DoseNotes
PAH — adults >12 yrs, body weight >40 kg62.5 mg BID for 4 weeks125 mg BID125 mg BIDMandatory 4-week uptitration; 250 mg BID not recommended (increased hepatotoxicity without additional benefit)
Take with or without food; do not split film-coated tablets
PAH — adults >12 yrs, body weight ≤40 kg62.5 mg BID62.5 mg BID62.5 mg BIDNo uptitration for lower weight patients
PAH with concurrent ritonavir (already on ritonavir ≥10 days)62.5 mg once daily or every other dayBased on tolerability62.5 mg dailyRitonavir causes up to 48-fold initial increase in bosentan levels via OATP inhibition
If starting ritonavir while on bosentan: stop bosentan ≥36 h before ritonavir, then resume at reduced dose after ≥10 days
PAH with aminotransferase elevation >3–5x ULNReduce to 62.5 mg BID or interrupt; recheck ALT/AST q2wkIf levels normalize, may re-challenge at 62.5 mg BID with recheck within 3 days
Permanently stop if >8x ULN

Pediatric Dosing (≤12 years) — By Body Weight

Body WeightDoseFormulationNotes
≥4–8 kg16 mg BIDDispersible tabletNo titration period
>8–16 kg32 mg BIDDispersible tabletNo titration period
>16–24 kg48 mg BIDDispersible tabletNo titration period
>24–40 kg64 mg BIDDispersible tablet or film-coatedNo titration period
Clinical Pearl: Auto-Induction and Dosing

Bosentan induces its own metabolism through upregulation of CYP3A4 and CYP2C9. Over the first 3–5 days of repeated dosing, plasma concentrations decrease by approximately 50% due to a 2-fold increase in clearance. This auto-induction is one reason the initial 62.5 mg BID phase is 4 weeks: it allows the clinician to assess tolerability at a dose that produces relatively higher initial exposure before uptitrating to 125 mg BID.

PK

Pharmacology

Mechanism of Action

Bosentan is a sulfonamide-class, competitive dual endothelin receptor antagonist that blocks both ETA and ETB receptors, with a slightly higher affinity for ETA. In PAH, endothelin-1 (ET-1) concentrations are elevated in both plasma and lung tissue, driving vasoconstriction and vascular smooth muscle proliferation through ETA and ETB2 receptors. By blocking both receptor subtypes, bosentan reduces pulmonary vascular resistance, improves cardiac index, and decreases pulmonary artery pressure. Unlike selective ETA antagonists such as ambrisentan, bosentan also blocks ETB1-mediated vasodilation and ET-1 clearance in the endothelium, though the net clinical effect of dual versus selective blockade remains uncertain from comparative outcome data.

ADME Profile

ParameterValueClinical Implication
AbsorptionBioavailability ~50%; Tmax 3–5 h; food does not clinically affect absorption; dose-linear PK up to 500 mg/dayCan be taken with or without food; twice-daily dosing required due to short half-life
DistributionVd ~18 L; >98% protein bound (albumin); does not enter erythrocytes; substrate of OATP1B1, OATP1B3, OATP2B1OATP-mediated hepatic uptake is the rate-limiting step for clearance, explaining extreme sensitivity to OATP inhibitors (cyclosporine, ritonavir)
MetabolismCYP2C9 and CYP3A4 (possibly CYP2C19); 3 metabolites identified; Ro 48-5033 is active (~10–20% of parent effect); strong auto-inducer of CYP3A4 and CYP2C9Auto-induction causes ~50% decline in steady-state levels vs first dose; induces metabolism of co-administered CYP3A4/2C9 substrates (sildenafil, hormonal contraceptives, simvastatin, warfarin)
EliminationPrimarily biliary excretion; <3% in urine; t1/2 ~5 h (unchanged at steady state); total clearance ~8 L/h (single IV dose) rising to ~17 L/h at steady state due to auto-inductionShort half-life requires BID dosing; PAH patients have 2-fold higher exposure than healthy volunteers; renal impairment does not require dose adjustment
SE

Side Effects

≥10%Very Common
Adverse EffectIncidenceClinical Note
Respiratory tract infection22% (vs 17% placebo)Includes nasopharyngitis, URI, and lower RTI; mechanism unclear
Headache15% (vs 14% placebo)Vasodilatory; marginal excess over placebo; usually self-limiting
Edema11% (vs 9% placebo)Class effect; monitor for right heart failure decompensation; may need diuretics
Abnormal aminotransferases11% (>3x ULN; N=658 pooled; vs 2% placebo)From Boxed Warning pooled analysis; Table 3 reports 4% vs 2% in PAH placebo-controlled trials (N=258). Dose-dependent: 12% at 125 mg BID, 14% at 250 mg BID. Usually asymptomatic and reversible; requires mandatory monthly LFT monitoring
1-10%Common
Adverse EffectIncidenceClinical Note
Syncope5% (vs 4% placebo)May reflect vasodilation or PAH-related; evaluate hemodynamics if recurrent
Flushing4% (vs 3% placebo)Vasodilatory mechanism; tends to diminish
Hypotension4% (vs 2% placebo)Mean systemic BP decrease ~3–4 mmHg; rarely clinically significant at recommended doses
Sinusitis4% (vs 2% placebo)Related to vasodilation-mediated nasal congestion
Palpitations4% (vs 2% placebo)Likely secondary to vasodilation
Anemia3% (vs 0% placebo)Mean Hb decrease 0.9 g/dL; marked decrease (>15% to <11 g/dL) in 6% of patients at 125 mg BID; onset first weeks, stabilizes 4–12 weeks
Arthralgia4% (vs 2% placebo)Treat symptomatically
SeriousSerious (Regardless of Frequency)
Adverse EffectEstimated FrequencyTypical OnsetRequired Action
Hepatotoxicity (ALT/AST >3x ULN)11%Both early and late; may occur at any pointFollow Table 2 dose-reduction algorithm; stop permanently if >8x ULN or if accompanied by symptoms or bilirubin ≥2x ULN
Hepatic cirrhosis / liver failureRare (postmarketing)>12 months of treatmentReinforces mandatory monthly LFT monitoring for entire duration of therapy; discontinue if signs of liver injury
Embryo-fetal toxicityExpected if exposedFirst trimesterAbsolute contraindication; monthly pregnancy testing; two forms of contraception required (hormonal contraception unreliable as sole method due to CYP induction)
Anemia requiring transfusionRare (postmarketing)First weeks to monthsInvestigate cause; consider discontinuation if marked and unexplained
Hypersensitivity (angioedema, DRESS, rash)Rare (postmarketing)8 hours to 21 days after initiationDiscontinue permanently; standard allergy management
Decreased sperm count (≥50% decline)25% in open-label study3–6 monthsCounsel males before initiation; reversible after discontinuation in reported cases
DiscontinuationDiscontinuation Rates
Adults (Placebo-Controlled PAH Trials)
6% vs 3% placebo
Primary cause: Abnormal liver function (only cause >1%)
Pediatric (Uncontrolled Studies)
Similar to adults
Safety profile consistent with adult PAH population
Managing Hepatotoxicity — The Dose-Reduction Algorithm

Hepatotoxicity is the defining safety concern for bosentan. Monthly ALT/AST monitoring is mandatory throughout treatment. If ALT/AST rises to >3–5x ULN, reduce to 62.5 mg BID or interrupt, then rechallenge at 62.5 mg BID once levels normalize, with recheck within 3 days. If >5–8x ULN, stop and consider reintroduction at 62.5 mg BID only after normalization. If >8x ULN, discontinue permanently. If any elevation is accompanied by clinical symptoms (jaundice, nausea, fever, abdominal pain, fatigue) or bilirubin ≥2x ULN, stop permanently with no rechallenge.

Int

Drug Interactions

Bosentan has one of the most complex drug interaction profiles of any PAH therapy. It is both a substrate and an inducer of CYP3A4 and CYP2C9, and a substrate of hepatic OATP transporters. This dual role as a CYP inducer means it reduces the exposure of many co-administered medications, while being highly sensitive to drugs that inhibit its hepatic uptake via OATP (cyclosporine, ritonavir).

MajorCyclosporine A
MechanismOATP inhibition markedly increases bosentan trough levels (~30-fold increase on first day of co-administration)
EffectDangerously elevated bosentan exposure; cyclosporine levels may also be reduced
ManagementCONTRAINDICATED — do not co-administer
FDA PI
MajorGlyburide
MechanismIncreased incidence of liver aminotransferase elevations when co-administered; bosentan also reduces glyburide levels
EffectElevated hepatotoxicity risk plus reduced hypoglycemic efficacy
ManagementCONTRAINDICATED — use alternative antidiabetic agents
FDA PI
MajorRitonavir / Lopinavir
MechanismPotent OATP inhibition causes ~48-fold increase in bosentan trough on Day 4, settling to ~5-fold by Day 10
EffectMarkedly increased bosentan exposure; risk of hepatotoxicity and adverse effects
ManagementSpecial dosing: reduce bosentan to 62.5 mg once daily or every other day; see ritonavir dosing section in PI
FDA PI
MajorHormonal Contraceptives (oral, injectable, implantable)
MechanismCYP3A4 induction by bosentan reduces estrogen and progestin exposure
EffectReduced contraceptive efficacy — hormonal methods alone are unreliable
ManagementMust use TWO forms of contraception; IUD or tubal sterilization acceptable as sole method; hormonal method requires addition of a barrier method
FDA PI
ModerateSildenafil
MechanismBosentan induces CYP3A4, reducing sildenafil AUC by ~63%; sildenafil increases bosentan levels by ~50%
EffectSubstantially reduced sildenafil exposure; modest bosentan increase
ManagementNo formal dose adjustment per FDA PI; however, clinical effect of sildenafil may be reduced — monitor PAH response
FDA PI
ModerateWarfarin
MechanismCYP2C9 induction may reduce S-warfarin exposure
EffectPotential reduction in anticoagulant effect (unlike ambrisentan, which has no warfarin interaction)
ManagementMonitor INR closely when initiating, adjusting, or discontinuing bosentan; warfarin dose increases may be needed
FDA PI / Lexicomp
ModerateSimvastatin / CYP3A4-Metabolized Statins
MechanismCYP3A4 induction reduces statin exposure by ~50%
EffectReduced cholesterol-lowering efficacy
ManagementMonitor lipid panel; consider statin dose increase or switch to rosuvastatin (less CYP3A4 dependent)
FDA PI
ModerateKetoconazole (and dual CYP2C9 + CYP3A4 inhibitors)
MechanismCYP3A4 inhibition increases bosentan AUC ~2-fold; co-inhibition of both CYP2C9 and CYP3A4 likely leads to larger increases
EffectIncreased bosentan exposure and hepatotoxicity risk
ManagementCombination of a CYP2C9 inhibitor + strong/moderate CYP3A4 inhibitor with bosentan is not recommended
FDA PI
Mon

Monitoring

  • Liver Aminotransferases (ALT/AST)Baseline, then monthly throughout treatment
    Routine
    MANDATORY under REMS. 11% of patients develop >3x ULN elevations. Follow dose-adjustment algorithm if elevated. Discontinue if symptomatic or bilirubin ≥2x ULN. Monthly monitoring continues for entire treatment duration — no exemptions regardless of treatment length.
  • Pregnancy TestBaseline, then monthly
    Routine
    Required under REMS for all females of reproductive potential. Must also test 1 month after stopping therapy. Two forms of contraception mandatory (hormonal methods unreliable as sole method due to CYP3A4 induction).
  • Hemoglobin / HematocritBaseline, 1 month, 3 months, then q3 months
    Routine
    Mean Hb decrease ~0.9 g/dL. Marked decrease (>15% from baseline to <11 g/dL) in 6% at 125 mg BID. Onset first weeks; stabilizes by 4–12 weeks. Investigate other causes if marked drop.
  • Functional Capacity (6MWD, WHO FC)Baseline, 3–6 months, then periodically
    Routine
    Improvement in walk distance expected by 4–8 weeks, fully developed by ~2 months. If declining, consider combination therapy escalation.
  • INR (if on warfarin)When initiating or changing bosentan
    Trigger-based
    CYP2C9 induction may reduce warfarin efficacy; recheck INR within 1–2 weeks of starting or stopping bosentan and adjust warfarin dose accordingly.
CI

Contraindications & Cautions

Absolute Contraindications

  • Pregnancy: Bosentan is teratogenic in rats at doses near human therapeutic levels. Major birth defects are expected. Two forms of contraception are required; hormonal methods unreliable as sole method due to CYP3A4 induction of estrogen/progestin metabolism.
  • Co-administration with cyclosporine A: Markedly increases bosentan trough levels (~30-fold on first day) via OATP inhibition. Contraindicated.
  • Co-administration with glyburide: Increased risk of hepatic aminotransferase elevations. Contraindicated.
  • Hypersensitivity to bosentan or excipients: Observed reactions include DRESS, anaphylaxis, angioedema, and rash.

Relative Contraindications (Specialist Input Recommended)

  • Baseline ALT/AST >3x ULN: Initiation should generally be avoided because monitoring for additional hepatotoxicity is more difficult when baseline values are already elevated.
  • Moderate or severe hepatic impairment (Child-Pugh B or C): Exposure increased ~4.7-fold in moderate impairment; not studied in severe impairment.

Use with Caution

  • WHO Functional Class II patients: The FDA PI specifically notes that the benefits of bosentan should be weighed against the risk of hepatotoxicity in milder disease, which could preclude future use of the drug if disease progresses.
  • Males desiring fertility: 25% of patients showed ≥50% sperm count decline in a dedicated study; reversible after discontinuation.
  • Patients on multiple CYP3A4/2C9 substrates: Bosentan will reduce their efficacy (statins, contraceptives, warfarin, sildenafil).
FDA Boxed Warning Hepatotoxicity and Embryo-Fetal Toxicity

Bosentan carries a dual boxed warning for hepatotoxicity and embryo-fetal toxicity. In clinical studies, ALT/AST elevations >3x ULN occurred in approximately 11% of patients. Rare cases of unexplained hepatic cirrhosis and liver failure have been reported in postmarketing surveillance after prolonged (>12 months) use. Bosentan is only available through the Bosentan REMS Program, which requires prescriber, patient, and pharmacy enrollment. Monthly LFT and pregnancy testing are mandated by the REMS. As of 2025, the FDA revised the REMS to remove components related specifically to embryo-fetal toxicity for ERAs after review of human pregnancy data, but the hepatotoxicity REMS requirements and pregnancy contraindication in the label remain fully in effect.

Pt

Patient Counselling

Purpose of Therapy

Bosentan blocks endothelin, a substance that narrows blood vessels in the lungs. It is taken twice daily to lower pressure in the lung arteries, improve the ability to exercise, and slow disease progression. It does not cure PAH but is a key part of long-term management.

How to Take

Take one tablet in the morning and one in the evening, with or without food. Do not stop taking bosentan suddenly without consulting your doctor, as symptoms may worsen. If a dose is missed, take it as soon as remembered but do not double the dose. Store at room temperature.

Liver Monitoring (Critical)
Tell patientMonthly blood tests for liver function are required by law for the entire time you take this medication. Liver damage may occur without symptoms. These tests allow early detection so the dose can be adjusted or the medication stopped safely.
Call prescriberImmediately if experiencing nausea, vomiting, stomach pain, fever, unusual tiredness, dark urine, or yellowing of the skin or eyes.
Pregnancy Prevention (Critical)
Tell patientBosentan causes serious birth defects. You must use two reliable forms of birth control at the same time because this medication reduces the effectiveness of birth control pills, patches, shots, and implants. Monthly pregnancy tests are required. If an IUD or tubal sterilization is in place, no additional contraception is needed.
Call prescriberImmediately if pregnancy is suspected or if a menstrual period is missed.
Swelling and Fluid Retention
Tell patientSwelling of the legs, ankles, or feet may occur. Weigh yourself regularly and report rapid weight gain.
Call prescriberIf swelling worsens rapidly, breathing becomes more difficult, or weight increases by more than 2–3 kg over a few days.
Anemia and Blood Count Changes
Tell patientThis medication can lower red blood cell levels. Blood tests will be done at 1 month, 3 months, and every 3 months thereafter. Report unusual fatigue or paleness.
Call prescriberIf experiencing significant new fatigue, shortness of breath at rest, or dizziness.
Drug Interactions
Tell patientBosentan interacts with many medications including blood thinners, cholesterol drugs, HIV medications, and antifungals. Always inform any healthcare provider that you are taking bosentan before starting a new medication.
Call prescriberBefore starting or stopping any new medication, including over-the-counter products or supplements.
Ref

Sources

Regulatory (PI / SmPC)
  1. TRACLEER (bosentan) tablets / tablets for oral suspension. Full Prescribing Information. Actelion Pharmaceuticals / Janssen. Revised July 2025. FDA Label (2025)Primary reference for all dosing, REMS requirements, adverse reactions, hepatotoxicity algorithm, and drug interactions.
  2. Bosentan tablets (generic). DailyMed. DailyMedGeneric label with identical adverse reaction data and monitoring requirements.
Key Clinical Trials
  1. Channick RN, Simonneau G, Sitbon O, et al. Effects of the dual endothelin-receptor antagonist bosentan in patients with pulmonary hypertension: a randomised placebo-controlled study. Lancet. 2001;358(9288):1119-1123. doi:10.1016/S0140-6736(01)06250-XStudy 351: first randomized trial of bosentan in PAH; established proof of concept for oral ERA therapy.
  2. Rubin LJ, Badesch DB, Barst RJ, et al. Bosentan therapy for pulmonary arterial hypertension. N Engl J Med. 2002;346(12):896-903. doi:10.1056/NEJMoa012212BREATHE-1: pivotal phase III trial (N=213) establishing 6MWD improvement and time-to-clinical-worsening benefit at 125 mg BID.
  3. Galiè N, Beghetti M, Gatzoulis MA, et al. Bosentan therapy in patients with Eisenmenger syndrome: a multicenter, double-blind, randomized, placebo-controlled study. Circulation. 2006;114(1):48-54. doi:10.1161/CIRCULATIONAHA.106.630715BREATHE-5: demonstrated safety and efficacy in Eisenmenger syndrome without worsening oxygen saturation.
  4. Galiè N, Rubin LJ, Hoeper MM, et al. Treatment of patients with mildly symptomatic pulmonary arterial hypertension with bosentan (EARLY study). Lancet. 2008;371(9630):2093-2100. doi:10.1016/S0140-6736(08)60919-8EARLY trial: showed PVR reduction and delayed time to clinical worsening in WHO FC II patients.
Guidelines
  1. Humbert M, Kovacs G, Hoeper MM, et al. 2022 ESC/ERS Guidelines for the diagnosis and treatment of pulmonary hypertension. Eur Heart J. 2022;43(38):3618-3731. doi:10.1093/eurheartj/ehac237Current comprehensive guideline positioning ERAs within PAH treatment algorithms and risk stratification.
  2. Klinger JR, Elliott CG, Levine DJ, et al. Therapy for pulmonary arterial hypertension in adults: update of the CHEST guideline. Chest. 2019;155(3):565-586. doi:10.1016/j.chest.2018.11.030CHEST 2019 guideline with recommendations for ERA monotherapy and combination approaches.
Mechanistic / Basic Science
  1. Clozel M, Breu V, Gray GA, et al. Pharmacological characterization of bosentan, a new potent orally active nonpeptide endothelin receptor antagonist. J Pharmacol Exp Ther. 1994;270(1):228-235. PMID:8035319Foundational preclinical study characterizing bosentan as a dual ET receptor antagonist with in vivo activity.
Pharmacokinetics / Special Populations
  1. Dingemanse J, van Giersbergen PLM. Clinical pharmacology of bosentan, a dual endothelin receptor antagonist. Clin Pharmacokinet. 2004;43(15):1089-1115. doi:10.2165/00003088-200443150-00003Comprehensive PK review: bioavailability, auto-induction, CYP interactions, special populations, and metabolite pharmacology.
  2. Bosentan. StatPearls [Internet]. Treasure Island (FL): StatPearls Publishing. Updated December 2025. NBK542293Comprehensive clinical review with updated 2025 REMS information and adverse effect synthesis.
  3. Weber C, Schmitt R, Birnboeck H, et al. Pharmacokinetics and pharmacodynamics of the endothelin-receptor antagonist bosentan in healthy human subjects. Clin Pharmacol Ther. 1996;60(2):124-137. doi:10.1016/S0009-9236(96)90127-7First-in-human PK/PD study establishing oral bioavailability (~50%), clearance, Vd, and ET-1 pharmacodynamic response.
  4. McLaughlin VV, Sitbon O, Badesch DB, et al. Survival with first-line bosentan in patients with primary pulmonary hypertension. Eur Respir J. 2005;25(2):244-249. doi:10.1183/09031936.05.00054804Long-term survival analysis of bosentan-treated patients from pivotal trials, showing 96% and 89% survival at 1 and 2 years respectively.