Drug Monograph

Diazepam

Valium, Diastat, Valtoco
Benzodiazepine·Oral · IV · IM · Rectal · Nasal·Schedule IV
Pharmacokinetic Profile
Half-Life
Up to 48 h (parent); up to 100 h (active metabolite)
Metabolism
CYP3A4 + CYP2C19; active metabolites
Protein Binding
98%
Bioavailability
>90% (oral)
Volume of Distribution
0.8–1.0 L/kg
Tmax
1–1.5 h (fasting); ~2.5 h (with food)
Clinical Information
Drug Class
Benzodiazepine
Available Doses
Tabs: 2, 5, 10 mg; Rectal gel: 2.5–20 mg; Nasal spray: 5, 7.5, 10 mg
Route
PO, IV, IM, Rectal, Intranasal
Renal Adjustment
Caution — metabolites accumulate in elderly
Hepatic Adjustment
Contraindicated in severe insufficiency; t½ 2–5x prolonged in cirrhosis
Pregnancy
Teratogenic in animals; neonatal risks
Lactation
Not recommended
Schedule
C-IV (Controlled)
Generic Available
Yes
Black Box Warning
Yes — 3 warnings
Rx

Indications

IndicationApproved PopulationTherapy TypeStatus
Anxiety disorders / short-term relief of anxiety symptomsAdults and children ≥6 monthsMonotherapyFDA Approved
Acute alcohol withdrawal (agitation, tremor, delirium tremens, hallucinosis)AdultsMonotherapyFDA Approved
Skeletal muscle spasm (reflex spasm, upper motor neuron spasticity, athetosis, stiff-person syndrome)Adults and children ≥6 monthsAdjunctiveFDA Approved
Convulsive disorders (adjunct)Adults and children ≥6 monthsAdjunctive (not sole therapy)FDA Approved
Acute seizure rescue (rectal gel / nasal spray)Ages ≥2 years (Diastat); ≥6 years (Valtoco)Acute intermittent rescueFDA Approved

Diazepam is the prototypical benzodiazepine with the broadest range of FDA-approved indications among the class. Its high lipid solubility enables rapid CNS penetration (onset within minutes via IV), but also leads to quick redistribution away from the brain after single doses, limiting anticonvulsant duration to approximately 20–30 minutes following IV administration. This contrasts with lorazepam, which has a longer duration of anticonvulsant action. Diazepam produces multiple pharmacologically active metabolites — notably N-desmethyldiazepam (half-life up to 100 hours), temazepam, and oxazepam — which contribute to its prolonged clinical effects and pronounced accumulation with repeated dosing. Long-term efficacy beyond 4 months has not been established for anxiety.

Off-Label Uses

ICU sedation: Continuous or intermittent IV infusion for mechanically ventilated patients. Evidence quality: Moderate.

Paediatric spasticity (cerebral palsy): Used for short-term spasticity management. Evidence quality: Moderate.

Procedural sedation: IV diazepam for endoscopy, cardioversion, and minor surgical procedures. Evidence quality: High (long clinical experience).

Benzodiazepine-responsive movement disorders: Including stiff-person syndrome variants. Evidence quality: Moderate.

Dose

Dosing

Oral Dosing — Adults

Clinical ScenarioStarting DoseMaintenance DoseMaximum DoseNotes
Anxiety — mild2 mg BID–TID2–5 mg BID–QIDUsual upper: 40 mg/dayIndividualise; use lowest effective dose; PI notes some may need higher
Efficacy beyond 4 months not established (FDA PI)
Anxiety — moderate to severe5 mg BID–QID5–10 mg BID–QIDUsual upper: 40 mg/dayDepending on severity of symptoms (FDA PI: 2–10 mg, 2–4 times daily)
Increase cautiously to avoid adverse effects
Acute alcohol withdrawal10 mg TID–QID5 mg TID–QID as needed30–40 mg/day (day 1)Loading in first 24 hours (10 mg 3–4x), then reduce to 5 mg 3–4x daily
Symptom-triggered dosing via CIWA-Ar may be preferred
Skeletal muscle spasm2 mg TID–QID2–10 mg TID–QIDUsual upper: 40 mg/dayIncludes reflex spasm, spasticity (cerebral palsy, paraplegia), stiff-person syndrome
Long-term use may require tolerance assessment
Adjunct in convulsive disorders2 mg BID–QID2–10 mg BID–QIDUsual upper: 40 mg/dayNot effective as sole therapy; add to existing anticonvulsant
Abrupt withdrawal may worsen seizures

Special Populations — Oral

Clinical ScenarioStarting DoseMaintenance DoseMaximum DoseNotes
Elderly or debilitated patients2–2.5 mg once or twice dailyIncrease gradually as neededLowest effectivet½ increases ~1 hour per year of age from 20 h at age 20
Extensive accumulation of parent drug and metabolites in elderly
Paediatric (≥6 months)1–2.5 mg TID–QIDIncrease gradually as neededIndividualiseInitiate with lowest dose; not for use <6 months
Paradoxical reactions more common in children

Rectal and Nasal — Seizure Rescue

Clinical ScenarioStarting DoseMaintenance DoseMaximum DoseNotes
Seizure rescue — rectal gel (Diastat; ≥2 years)0.2–0.5 mg/kg (age-based)Repeat after 4–12 h if needed20 mg/dose; max 2 doses/episodeRound to nearest 2.5 mg increment; ≤5 episodes/month
2–5 yr: 0.5 mg/kg; 6–11 yr: 0.3 mg/kg; ≥12 yr: 0.2 mg/kg
Seizure rescue — nasal spray (Valtoco; ≥6 years)5, 7.5, or 10 mg (weight-based)Second dose after ≥4 h if needed2 doses/episode; ≤5 episodes/monthOne spray per nostril (alternating nostrils for 2-spray doses)
Not for daily use; intended for intermittent rescue only
Clinical Pearl: Active Metabolites and Accumulation

Diazepam produces three pharmacologically active metabolites: N-desmethyldiazepam (t½ up to 100 hours), temazepam, and oxazepam. With repeated dosing, parent drug and metabolites accumulate substantially — particularly in elderly patients and those with hepatic impairment. An elderly patient who appears well on day 1 may develop progressive sedation, confusion, and ataxia over days to weeks as steady-state concentrations build. This accumulation profile is a key reason clinicians may prefer lorazepam or oxazepam in elderly or hepatically impaired patients, since those agents undergo direct glucuronidation without CYP-dependent metabolism or active metabolite formation.

PK

Pharmacology

Mechanism of Action

Diazepam is the prototypical 1,4-benzodiazepine that facilitates the action of GABA, the major inhibitory neurotransmitter in the CNS. By binding to the benzodiazepine allosteric site on the GABA-A receptor, diazepam increases the frequency of chloride channel opening in the presence of GABA, resulting in neuronal hyperpolarisation. This produces its characteristic spectrum of anxiolytic, sedative, muscle-relaxant, anticonvulsant, and amnestic effects. Diazepam acts on parts of the limbic system, the thalamus, and the hypothalamus. Unlike antipsychotics, it has no demonstrable peripheral autonomic blocking action and does not produce extrapyramidal side effects. Its high lipid solubility enables rapid crossing of the blood-brain barrier, accounting for its fast onset of action, but also causes rapid redistribution to peripheral fat stores after single IV doses, limiting the duration of acute CNS effects.

ADME Profile

ParameterValueClinical Implication
Absorption>90% absorbed orally; Tmax 1–1.5 h (fasting), ~2.5 h (with food); food decreases Cmax by 20% and AUC by 27%Rapid oral onset; food delays and reduces peak levels but does not affect clinical significance for most indications
DistributionVd 0.8–1.0 L/kg (young adults); 98% protein bound; crosses placenta, blood-brain barrier, and enters breast milk (~1/10 maternal plasma levels)Highly lipophilic; rapid CNS penetration then redistribution to fat; Vd increases with age and hepatic disease; elderly have lower peak but higher trough on chronic dosing
MetabolismN-demethylation via CYP3A4 and CYP2C19 to N-desmethyldiazepam (active, t½ up to 100 h); hydroxylation via CYP3A4 to temazepam (active); both further metabolised to oxazepam (active) and then glucuronidatedMultiple CYP-dependent steps create extensive drug interaction potential; 3 active metabolites cause prolonged clinical effect and accumulation; inhibitors of CYP3A4 or CYP2C19 significantly increase exposure
Eliminationt½ up to 48 h (parent); N-desmethyldiazepam t½ up to 100 h; clearance 20–30 mL/min (young adults); excreted mainly in urine as glucuronide conjugatesElderly: t½ increases ~1 h/year of age; cirrhosis: 2–5x increase in t½ (individual values >500 h reported); children 3–8 yr: mean t½ 18 h; neonates: t½ ~30–54 h
SE

Side Effects

Most CommonMost Commonly Reported (FDA PI)
Adverse EffectIncidenceClinical Note
DrowsinessMost commonDose-dependent; enhanced by active metabolites; may persist longer than expected due to accumulation
FatigueVery commonOverlaps with drowsiness; may worsen with repeated dosing as metabolites accumulate
Muscle WeaknessVery commonReflection of muscle-relaxant properties; fall risk in elderly and debilitated patients
AtaxiaVery commonDose-related; significant contributor to falls and fractures (post-marketing reports)

Note: The FDA Valium oral PI lists “most commonly reported” adverse effects without specific incidence percentages from placebo-controlled trials. The above effects are identified as the most frequent based on the PI’s adverse reactions section and extensive clinical experience.

Also ReportedOther Recognised Adverse Effects
Adverse EffectIncidenceClinical Note
ConfusionReportedMore common in elderly; may mimic or worsen delirium; enhanced by metabolite accumulation
DepressionReportedPre-existing depression may emerge; protective measures may be necessary in at-risk patients
Dysarthria / Slurred SpeechReportedDose-dependent; sign of excessive CNS depression
Blurred Vision / DiplopiaReportedVisual disturbance; may impair driving
Dizziness / VertigoReportedContributes to fall risk
HypotensionReportedMore relevant with IV administration; may be orthostatic
Constipation / NauseaReportedGI disturbance generally mild
Anterograde AmnesiaReportedOccurs at therapeutic doses; risk increases with dose; may be associated with inappropriate behaviour
Changes in Libido / Urinary RetentionReportedUrogenital effects including incontinence
Changes in SalivationReportedBoth dry mouth and hypersalivation described
SeriousSerious Adverse Effects
Adverse EffectEstimated FrequencyTypical OnsetRequired Action
Physical Dependence / Withdrawal (including seizures)Common with prolonged useOn abrupt discontinuationNever stop abruptly; gradual taper essential; withdrawal may include tremor, cramps, vomiting, sweating, seizures, psychosis
Respiratory DepressionDose-dependent; higher with IV and opioid co-useMinutes (IV); hours (oral)Discontinue; ventilatory support; flumazenil as adjunct (caution in long-term BZD users and epilepsy)
Paradoxical Reactions (rage, hallucinations, psychosis, agitation)RareAny time; more common in children and elderlyDiscontinue diazepam
Falls and FracturesPost-marketing reportsOngoing; risk increased with concomitant sedatives and in elderlyFall risk assessment; consider deprescribing; physiotherapy
Neutropenia / JaundiceIsolated reportsVariablePeriodic blood counts and LFTs on long-term therapy (FDA PI)
Neonatal Flaccidity / Respiratory DepressionExpected with late-pregnancy or labour exposureBirth / neonatal periodMonitor neonate; immature metabolic pathways prolong drug effects in neonates (t½ ~30–54 h)
DiscontinuationWithdrawal & Discontinuation
Withdrawal Symptoms
Barbiturate-type
Acute: Tremor, cramps, vomiting, sweating, headache, anxiety, tension, confusion, seizures
Protracted Withdrawal
Weeks to >12 months
Features: Anxiety, cognitive impairment, depression, insomnia, paresthesia, tinnitus; may be difficult to distinguish from symptom recurrence
Accumulation Risk in Elderly Patients

Diazepam’s elimination half-life increases approximately 1 hour for every year of age starting from a baseline of ~20 hours at age 20. In a 75-year-old patient, the parent compound half-life may exceed 75 hours, and the active metabolite N-desmethyldiazepam may persist far longer. The AGS Beers Criteria identifies diazepam as a potentially inappropriate medication in older adults. Lorazepam or oxazepam (which are glucuronidated directly without active metabolites) are generally safer alternatives in this population.

Int

Drug Interactions

Diazepam is metabolised via CYP3A4 and CYP2C19, producing active metabolites through multiple oxidative steps before final glucuronidation. This creates a broad drug interaction profile — significantly wider than lorazepam (which bypasses CYP450 entirely) or even alprazolam (CYP3A4 only). Both pharmacokinetic and pharmacodynamic interactions are clinically important.

MajorOpioids (all)
MechanismAdditive CNS/respiratory depression via GABA-A and mu-opioid synergy
EffectProfound sedation, respiratory depression, coma, death
ManagementAvoid if possible; if essential, use lowest doses and shortest duration with close monitoring
FDA Boxed Warning
MajorAlcohol
MechanismAdditive GABAergic CNS depression
EffectEnhanced sedation, respiratory depression, impaired motor function
ManagementNot recommended; counsel at every visit
FDA PI
ModerateCYP3A4 / CYP2C19 Inhibitors (cimetidine, ketoconazole, fluvoxamine, fluoxetine, omeprazole)
MechanismInhibition of CYP3A4 and/or CYP2C19 reduces diazepam metabolism
EffectIncreased and prolonged sedation due to elevated diazepam concentrations
ManagementConsider dose reduction; monitor for excess sedation; alternative BZD (lorazepam) avoids this interaction
FDA PI
ModerateOther CNS Depressants
MechanismAdditive CNS depression
EffectIncreased sedation and respiratory depression
ManagementUse caution; includes phenothiazines, antipsychotics, barbiturates, MAOIs, TCAs, sedative antihistamines, narcotics, anaesthetics
FDA PI
ModeratePhenytoin
MechanismDiazepam may decrease metabolic elimination of phenytoin
EffectIncreased phenytoin levels with potential toxicity
ManagementMonitor phenytoin levels when co-administered
FDA PI
MinorAntacids
MechanismSlower rate of absorption (not extent)
Effect30% lower peak concentrations; 20–25 min delayed Tmax; total absorption unchanged
ManagementNot statistically significant; no dose adjustment needed
FDA PI
Mon

Monitoring

  • Sedation & Psychomotor FunctionEach visit; extra vigilance days 3–14
    Routine
    Active metabolites accumulate over 5–7 half-lives; peak sedation may not appear until days into therapy. Assess driving safety and cognitive performance.
  • Abuse / Misuse RiskBaseline, each visit
    Routine
    Standardised screening before prescribing. Monitor for dose escalation, early refill requests, multiple prescribers.
  • Mood & SuicidalityEach visit
    Routine
    Suicidal tendencies may be present in depressed patients; not recommended for psychotic patients; protective measures may be necessary.
  • CBC & Liver FunctionPeriodically on long-term therapy
    Routine
    Isolated reports of neutropenia and jaundice. Periodic blood counts and LFTs advisable (FDA PI). Hepatic impairment dramatically prolongs elimination.
  • Hepatic Function (if impaired)Baseline; ongoing
    Trigger-based
    Cirrhosis increases t½ 2–5 fold (individual t½ >500 h reported). Contraindicated in severe hepatic insufficiency. Hepatic encephalopathy may be precipitated.
  • Fall Risk (Elderly)Baseline, q3 months
    Routine
    Falls and fractures reported post-marketing. Risk increased with concomitant sedatives and alcohol. Beers Criteria lists diazepam as potentially inappropriate in older adults.
  • Respiratory FunctionBaseline; ongoing in COPD/sleep apnoea
    Trigger-based
    Lower doses recommended in chronic respiratory insufficiency. Contraindicated in severe respiratory insufficiency and sleep apnoea syndrome.
  • Treatment Duration Reviewq3 months
    Routine
    Efficacy beyond 4 months not established. Tolerance may develop. Document clinical justification for continued use.
CI

Contraindications & Cautions

Absolute Contraindications

  • Known hypersensitivity to diazepam
  • Paediatric patients <6 months (insufficient clinical experience)
  • Myasthenia gravis
  • Severe respiratory insufficiency
  • Severe hepatic insufficiency
  • Sleep apnoea syndrome
  • Acute narrow-angle glaucoma (may use in open-angle glaucoma with appropriate therapy)

Relative Contraindications (Specialist Input Recommended)

  • Psychotic disorders — not recommended; should not replace appropriate treatment
  • Severe depression — suicidal tendencies may be present; protective measures needed
  • Active substance use disorder — addiction-prone individuals require careful surveillance
  • Pregnancy — teratogenic in mice/hamsters at high doses; neonatal flaccidity, respiratory depression, and withdrawal with late-pregnancy use

Use with Caution

  • Elderly patients — extensive accumulation; initial 2–2.5 mg QD–BID; AGS Beers Criteria potentially inappropriate medication
  • Mild-moderate hepatic impairment — 2–5 fold t½ increase; reduced clearance
  • Renal impairment (elderly) — metabolite accumulation; toxicity risk increased
  • Chronic respiratory insufficiency — lower dose recommended; risk of respiratory depression
  • History of alcohol or drug abuse — use extreme caution
FDA Boxed WarningRisks from Concomitant Use with Opioids

Combined use of benzodiazepines and opioids may result in profound sedation, respiratory depression, coma, and death. Reserve concomitant prescribing for patients with no adequate alternative. Use lowest doses for shortest duration.

FDA Boxed WarningAbuse, Misuse, and Addiction

Diazepam exposes users to risks of abuse, misuse, and addiction. Assess each patient’s risk before prescribing and throughout treatment.

FDA Boxed WarningDependence and Withdrawal Reactions

Continued use may lead to physical dependence. Abrupt discontinuation can precipitate life-threatening withdrawal reactions including seizures. Use gradual taper to discontinue.

Pt

Patient Counselling

Purpose of Therapy

Diazepam is prescribed to reduce anxiety, relieve muscle spasm, help manage alcohol withdrawal, or support seizure management. It works by calming overactive nerve signals in the brain. Because diazepam and its breakdown products stay in your body for a long time, effects can build up over several days of use. Regular check-ups with your prescriber are essential.

How to Take

Take diazepam exactly as prescribed. Tablets should be swallowed whole with water. Taking with food will delay the effect but does not change the overall amount absorbed. For seizure rescue (rectal gel or nasal spray), follow the specific instructions provided and ensure a caregiver is trained in administration. Store securely — diazepam is a controlled substance.

Drowsiness & Coordination
Tell patientDrowsiness, weakness, and unsteadiness are common and may worsen over the first few days as the drug accumulates. Do not drive or operate machinery until you know how diazepam affects you. Avoid alcohol completely.
Call prescriberIf drowsiness worsens over time (this may indicate accumulation), or if you experience falls or significant confusion.
Dependence & Withdrawal
Tell patientYour body can become physically dependent on diazepam. Never stop this medication suddenly — withdrawal can cause seizures and other dangerous symptoms. Your doctor will reduce the dose gradually when it is time to stop.
Call prescriberIf you experience increased anxiety, tremor, sweating, confusion, hallucinations, or seizures during any dose change.
Mood Changes
Tell patientDiazepam may unmask or worsen depression. Rarely, unexpected reactions such as agitation, aggression, or hallucinations can occur. Family members should be aware of these possibilities.
Call prescriberImmediately if you have thoughts of self-harm, feel significantly more depressed, or experience unusual agitation or hostility.
Pregnancy & Breastfeeding
Tell patientDiazepam may harm an unborn baby and passes into breast milk. Breastfeeding is not recommended. Contact your prescriber immediately if you become pregnant.
Call prescriberImmediately if you become pregnant or are planning pregnancy.
Seizure Rescue (Diastat / Valtoco)
Tell patientSeizure rescue formulations are for intermittent use only — not daily. Ensure your caregiver is trained in administration. Do not use more than 2 doses per seizure episode or more than 5 episodes per month.
Call prescriberIf seizures do not stop after administration, or if seizure frequency increases.
Ref

Sources

Regulatory (PI / SmPC)
  1. Valium (diazepam) Tablets. Full Prescribing Information. Genentech USA, Inc. Revised February 2021. FDA LabelPrimary source for all oral dosing, adverse reactions, pharmacokinetic data (including hepatic/geriatric special populations), drug interactions, and contraindications.
  2. Valium (diazepam) Tablets. Full Prescribing Information. Waylis Therapeutics LLC. Revised 2023. FDA Label (2023)Updated label with current boxed warnings (opioid co-use, abuse/misuse/addiction, dependence/withdrawal).
  3. Diastat (diazepam rectal gel). Full Prescribing Information. Bausch Health. DailyMedSource for age-based rectal rescue dosing (0.2–0.5 mg/kg) and seizure rescue administration guidelines.
Key Clinical Trials
  1. Treiman DM, Meyers PD, Walton NY, et al. A comparison of four treatments for generalized convulsive status epilepticus. N Engl J Med. 1998;339(12):792-798. DOIVA Cooperative Study comparing IV diazepam to lorazepam, phenobarbital, and phenytoin for SE; lorazepam found superior as first-line.
  2. Alldredge BK, Gelb AM, Isaacs SM, et al. A comparison of lorazepam, diazepam, and placebo for the treatment of out-of-hospital status epilepticus. N Engl J Med. 2001;345(9):631-637. DOIPrehospital SE trial establishing both lorazepam and diazepam as effective vs placebo; diazepam has shorter anticonvulsant duration.
  3. Calcaterra NE, Barrow JC. Classics in chemical neuroscience: diazepam (Valium). ACS Chem Neurosci. 2014;5(4):253-260. DOIComprehensive historical and pharmacological review of diazepam covering its development, mechanism, and clinical impact.
Guidelines
  1. Glauser T, Shinnar S, Gloss D, et al. Evidence-based guideline: treatment of convulsive status epilepticus in children and adults. Epilepsy Curr. 2016;16(1):48-61. DOIAES guideline listing IV diazepam as Level A first-line for SE alongside IV lorazepam and IM midazolam.
  2. By the 2023 American Geriatrics Society Beers Criteria Update Expert Panel. American Geriatrics Society 2023 updated AGS Beers Criteria. J Am Geriatr Soc. 2023;71(7):2052-2081. DOILists all benzodiazepines, including diazepam, as potentially inappropriate in older adults due to cognitive impairment, delirium, falls, and fracture risk.
  3. Sachdeva A, Choudhary M, Chandra M. Alcohol withdrawal syndrome: benzodiazepines and beyond. J Clin Diagn Res. 2015;9(9):VE01-VE07. DOIReview supporting diazepam and chlordiazepoxide as first-choice agents for alcohol withdrawal due to their long half-lives providing smoother withdrawal profiles.
Mechanistic / Basic Science
  1. Rudolph U, Knoflach F. Beyond classical benzodiazepines: novel therapeutic potential of GABAA receptor subtypes. Nat Rev Drug Discov. 2011;10(9):685-697. DOIReview of GABA-A receptor subtype pharmacology explaining benzodiazepine anxiolytic, anticonvulsant, muscle-relaxant, and sedative effects.
Pharmacokinetics / Special Populations
  1. Greenblatt DJ, Shader RI, Divoll M, Harmatz JS. Benzodiazepines: a summary of pharmacokinetic properties. Br J Clin Pharmacol. 1981;11(Suppl 1):11S-16S. DOIDefinitive comparative PK review covering diazepam distribution, metabolism, and age-related changes in elimination.
  2. Sharbaf Shoar N, Bistas KG, Patel P, Saadabadi A. Diazepam. In: StatPearls [Internet]. Treasure Island (FL): StatPearls Publishing; 2024 Jan–. Updated February 29, 2024. NCBI BookshelfCurrent clinician-oriented review covering all approved indications, off-label uses, dosing across routes, and special populations.